Випуски $\rightarrow$ Том 25, випуск 3 (2024)

Вплив леґування на воднесорбційні властивості стопів на основі Ti–Zr–Mn. Ч. 1: Стопи на основі Лавесової фази типу C14

ДЕХТЯРЕНКО В.А.$^{1,2}$, ПРЯДКО Т.В.$^{1}$, ВЛАДІМІРОВА Т.П.$^{1}$, МАКСИМОВА С.В.$^{2}$, МИХАЙЛОВА Г.Ю.$^{1}$, БОНДАРЧУК В.І.$^{1}$

$^1$Інститут металофізики ім. Г.В. Курдюмова НАН України, бульв. Академіка Вернадського, 36, 03142 Київ, Україна
$^2$Інститут електрозварювання ім. Є.О. Патона НАН України, вул. Казимира Малевича, 11, 03150 Київ, Україна

Отримано 12.03.2024, остаточна версія 05.08.2024 Завантажити PDF logo PDF

Анотація
Стопи на основі Лавесової фази типу C14 у системі Ti–Zr–Mn вважаються одними з найперспективніших матеріялів для безпечного зберігання та транспортування водню у зв’язаному стані. Вони мають відносно «м’які» параметри для активації процесів поглинання та виділення водню, невисоку собівартість, а також достатньо високу циклічну стабільність. У даній роботі розглядаються мікроструктура та фазовий склад вихідних стопів і кристалічна структура синтезованих гідридів на їхній основі. Демонструються можливі шляхи пониження собівартости кінцевого продукту, а також той факт, що зміна способу одержання стопу не впливає істотно на його воднесорбційні властивості. Також на прикладі розглянутих стопів показано, що леґування стопу елементом з більшим атомним радіюсом і здатним утворювати стійку хемічну сполуку з Гідроґеном, очікувано приведе до збільшення водневої місткости. Це досягається завдяки збільшенню радіюса тетраедричних міжвузловин, де локалізуються атоми Гідроґену під час розчинення, та підвищенню у складі стопу загальної кількости елементу, здатного взаємодіяти з Гідроґеном.

Ключові слова: Лавесова фаза, інтерметалід, леґувальний елемент, тетраедричні міжвузловини, гідрування–дегідрування, воднева місткість.

DOI: https://doi.org/10.15407/ufm.25.03.520

Citation: V.A. Dekhtyarenko, T.V. Pryadko, T.P. Vladimirova, S.V. Maksymova, H.Yu. Mykhailova, and V.I. Bondarchuk, Effect of Alloying on the Hydrogen Sorption in Ti–Zr–Mn-Based Alloys. Pt. 1: C14-Type Laves-Phase-Based Alloys, Progress in Physics of Metals, 25, No. 3: 520–544 (2024)

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