Воднева крихкість титану: прояви та основні шляхи запобігання

ДЕХТЯРЕНКО В.А.$^{1,2}$, ПРЯДКО Т.В.$^{1}$, БОШКО О.І.$^{1}$, КИРИЛЬЧУК В.В.$^{1}$, МИХАЙЛОВА Г.Ю.$^{1}$, БОНДАРЧУК В.І.$^{1}$

$^1$Інститут металофізики ім. Г.В. Курдюмова НАН України, бульв. Академіка Вернадського, 36, 03142 Київ, Україна
$^2$Інститут електрозварювання ім. Є.О. Патона НАН України, вул. Казимира Малевича, 11, 03150 Київ, Україна

Отримано 10.01.2024, остаточна версія 22.04.2024 Завантажити PDF logo PDF

Анотація
Робота стосується питання про погіршення механічних властивостей металевих матеріалів (на прикладі Ti) в присутності водню (воднева крихкість). Визначено три основні форми руйнування через присутність водню в металевих матеріалах. Перша — пошкодження у внутрішніх порах, тріщинах, що виникають через захоплення бульбашок газоподібного водню в процесі затвердіння розтопу або дифузії Гідроґену через металеву ґратницю. Другу форму спричинено Гідроґеном, що утворює гідриди та змінює тип кристалічної ґратки металу. Третя форма включає решту руйнувань, пов’язаних із присутністю Гідроґену в об’ємі матеріалу в умовах довготривалих статичних навантажень. Встановлено основні методи унеможливлення реакції взаємодії металевих матеріалів із Гідроґеном: (1) легування, що зменшує швидкість взаємодії металевого матеріалу з Гідроґеном, (2) модифікування поверхні методами високоенергетичного впливу, (3) нанесення захисних покриттів, (4) відпал вже готових виробів.

Ключові слова: титан, воднева крихкість, захисні покриття, модифікування поверхні, структура, гідрид.

DOI: https://doi.org/10.15407/ufm.25.02.276

Citation: V.A. Dekhtyarenko, T.V. Pryadko, О.І. Boshko, V.V. Kirilchuk, H.Yu. Mykhailova, and V.I. Bondarchuk, Hydrogen Embrittlement of Titanium: Phenomena and Main Ways of Prevention, Progress in Physics of Metals, 25, No. 2: 276–293 (2024)


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