Випуски $\rightarrow$ Том 24, випуск 3 (2023)

Про розчинність Гідроґену у металах і стопах

Ан. Д. Золотаренко$^{1,2}$, Ол. Д. Золотаренко$^{1,2}$, 3. А. Матисіна$^1$, Н. А. Швачко$^{1,3}$, Н. Є. Аханова$^{4,5}$, M. Уалханова$^5$, Д. В. Щур$^{1,6}$, M. T. Габдуллін$^4$, Ю. І. Жирко$^6$, Ю. М. Солонін$^1$, В. В. Лобанов$^2$, Д. В. Ісмаїлов$^{5,7}$, О. Д. Золотаренко$^1$, І. В. Загорулько$^8$

$^1$Інститут проблем матеріалознавства ім. І. М. Францевича НАН України, вул. Омеляна Пріцака, 3, 03142 Київ, Україна
 $^2$Інститут хімії поверхні ім. О. О. Чуйка НАН України, вул. Генерала Наумова, 17, 03164 Київ, Україна
 $^3$Київський національний університет будівництва і архітектури, просп. Повітрофлотський, 31, 03037 Київ, Україна
 $^4$Казахстансько-британський технічний університет, вул. Толе бі, 59, 050040 Алмати, Казахстан
 $^5$Казахський національний університет ім. Аль-Фарабі, просп. Аль-Фарабі, 71, 050040 Алмати, Казахстан
 $^6$Інститут прикладної фізики НАН України, вул. Петропавлівська, 58, 40000 Суми, Україна
 $^7$НАТ «Казахський національний дослідницький технічний університет імені К.І. Сатбаєва», вул. Сатбаєва, 22, 050013 Алмати, Казахстан
 $^8$Інститут металофізики ім. Г. В. Курдюмова НАН України, бульв. Академіка Вернадського, 36, 03142 Київ, Україна

Отримано 13.07.2023; остаточна версія — 13.08.2023 Завантажити PDF logo PDF

Анотація
Оглянуто та проаналізовано чинники впливу на розчинність атомів втілення (H) у металевих стопах. Розглянуто електронну структуру й атомове впорядкування стопів типу АВ, а також методи розрахунку розчинности для упорядковних кубічних стопів з октаедричними порами втілення. Вивчено параметри атомів втілення, що уможливлюють прогноз зменшення або збільшення розчинности, коли головну роль відіграє впорядкування системи. Встановлено параметри статичного розподілу атомів. Розглянуто відносну розчинність як функцію параметра далекого порядку (η) та вплив об’ємних ефектів на величину цього параметра. Розглянуто наступні системи: Fe–Ni, Au–Cu, Pd–Au, Fe–Cr, Ti–Al, Cu–Zn, Ag–Zn, Fe–Al, Au–Ag, Fe–V, Pd–Pt, Ni–Mn, Ni–Fe, Cu–Au, Cu–Pd, Pd–Nb, Pd–Ag, а також трикомпонентні стопи. Показано, що шляхом введення домішок у стоп можна значною мірою змінити його фізико-механічні, електричні, магнетні й інші властивості.

Ключові слова: метали, стопи, атоми втілення, розчинність, упорядкування, об’ємноцентрована кубічна (ОЦК) структура, гранецентрована кубічна (ГЦК) структура, молекулярно-кінетична теорія.

DOI: https://doi.org/10.15407/ufm.24.03.415

Citation: An. D. Zolotarenko, Ol. D. Zolotarenko, Z. A. Matysina, N. A. Shvachko, N. Y. Akhanova, M. Ualkhanova, D. V. Schur, M. T. Gabdullin, Yu. I. Zhirko, Yu. M. Solonin, V. V. Lobanov, D. V. Ismailov, A. D. Zolotarenko, and I. V. Zagorulko, On the Solubility of Hydrogen in Metals and Alloys, Progress in Physics of Metals, 24, No. 3: 415–445 (2023)

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