Issues $\rightarrow$ Volume 24, Issue 3 (2023)

On the Solubility of Hydrogen in Metals and Alloys

An. D. Zolotarenko$^{1,2}$, Ol. D. Zolotarenko$^{1,2}$, Z. A. Matysina$^1$, N. A. Shvachko$^{1,3}$, N. Y. Akhanova$^{4,5}$, M. Ualkhanova$^5$, D. V. Schur$^{1,6}$, M. T. Gabdullin$^4$, Yu. I. Zhirko$^6$, Yu. M. Solonin$^1$, V. V. Lobanov$^2$, D. V. Ismailov$^{5,7}$, A. D. Zolotarenko$^1$, and I. V. Zagorulko$^8$

$^1$I. M. Frantsevych Institute for Problems of Materials Science of the N.A.S. of Ukraine, Omeljan Pritsak Str., UA-03142 Kyiv, Ukraine
 $^2$O. O. Chuiko Institute of Surface Chemistry of the N.A.S. of Ukraine, 17 General Naumov Str., UA-03164 Kyiv, Ukraine
 $^3$Kyiv National University of Construction and Architecture, 31 Povitroflotskyi Ave., UA-03037 Kyiv, Ukraine
 $^4$Kazakh–British Technical University, 59 Tole bi Str., 050000 Almaty, Kazakhstan
 $^5$Al-Farabi Kazakh National University, 71 Al-Farabi Ave., 050040 Almaty, Kazakhstan
 $^6$Institute of Applied Physics of the N.A.S. of Ukraine, 58 Petropavlivska Str., UA-40000 Sumy, Ukraine
 $^7$NJSC ‘K. I. Satbayev Kazakh National Research Technical University’, 22a Satbaev Str., 050013 Almaty, Kazakhstan
 $^8$G. V. Kurdyumov Institute for Metal Physics of the N.A.S. of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine

Received 13.07.2023; final version — 13.08.2023 Download PDF logo PDF

Abstract
We review and analyse the factors affecting the solubility of interstitial atoms (H) in the metal alloys. The electronic structure and atomic ordering of the AB-type alloys, as well as methods of calculation of the solubility for ordering cubic alloys with octahedral interstitial pores are considered. We study the parameters of interstitial atoms, which make it possible to predict a decrease or increase in solubility, when the main role belongs to the ordering of the system. The parameters of the static distribution of atoms are determined. The relative solubility is represented as a function of the long-range order parameter (η), and the influence of bulk effects on this parameter is considered. The following systems are studied: Fe–Ni, Au–Cu, Pd–Au, Fe–Cr, Ti–Al, Cu–Zn, Ag–Zn, Fe–Al, Au–Ag, Fe–V, Pd–Pt, Ni–Mn, Ni–Fe, Cu–Au, Cu–Pd, Pd–Nb, Pd–Ag, as well as three-component alloys. As shown, through introducing impurities into the alloy, we can change significantly its physical-mechanical, electrical, magnetic, and other properties.

Keywords: alloys, interstitial atoms, solubility, ordering, body-centred cubic (b.c.c.) structure, face-centred cubic (f.c.c.) structure, molecular kinetic theory.

DOI: https://doi.org/10.15407/ufm.24.03.415

Citation: An. D. Zolotarenko, Ol. D. Zolotarenko, Z. A. Matysina, N. A. Shvachko, N. Y. Akhanova, M. Ualkhanova, D. V. Schur, M. T. Gabdullin, Yu. I. Zhirko, Yu. M. Solonin, V. V. Lobanov, D. V. Ismailov, A. D. Zolotarenko, and I. V. Zagorulko, On the Solubility of Hydrogen in Metals and Alloys, Progress in Physics of Metals, 24, No. 3: 415–445 (2023)

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