Литі алюмінієві стопи як конкурентоспроможні сучасні конструкційні матеріяли: хемічний склад, виготовлення, обробка, випробування, механічні властивості та застосування

ЛЮТИЙ Р.В.$^{1}$, ПЕТРИК І.Я.$^{2}$, ІВАНЧЕНКО Д.В.$^{1}$, ЯМШИНСЬКИЙ М.М.$^{1}$, ЛУК’ЯНЕНКО І.В.$^{1}$, БИБА Є.Г.$^{1,3,4}$, КИВГИЛО Б.В.$^{1}$, ПЕТРИЧЕНКО С.В.$^{1}$, КОВАЛЕНКО В.В.$^{1}$, ЛЕОНОВ Д.С.$^{5}$, БАРАБАШ М.Ю.$^{1,4,5,6}$

$^1$Навчально-науковий інститут матеріалознавства та зварювання імені Є.О. Патона, Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського», проспект Берестейський, 37; 03056 Київ, Україна
$^2$Франківський національний технічний університет нафти і газу, вул. Карпатська, 15; 76019 Івано-Франківськ, Україна
$^3$Інститут електрозварювання ім. Є.О. Патона НАН України, вул. Казимира Малевича, 11; 03150 Київ, Україна
$^4$Інститут прикладних систем управління НАН України, проспект Академіка Глушкова, 42; 03187 Київ, Україна
$^5$Технічний центр НАН України, вул. Покровська, 13; 04070 Київ, Україна
$^6$Інститут газу НАН України, вул. Дегтярівська, 39; 03113 Київ, Україна

Отримано / остаточна версія: 19.05.2026 / 05.08.2026 Завантажити PDF logo PDF

Анотація
У статті наведено огляд сучасних алюмінійових стопів, технологій, що використовуються для виробництва й оброблення їх, а також формування їхньої мікроструктури та властивостей. Наразі машинобудування має тенденцію до широкого використання ресурсоефективних, екологічно чистих і високоточних технологій. Оскільки алюмінійові стопи мають низьку густину, відносно високу міцність, достатню пластичність і певні особливі властивості (достатньо високу міцність за підвищених температур), вони є ідеальними матеріялами для широкого використання в автомобільній, приладобудівній та аерокосмічній промисловостях. Наведено класифікацію алюмінійових стопів з різними групами на основі леґувальних елементів. Проведено аналогії між національною (українською) класифікацією стопів і тими, що використовуються в провідних промислово розвинених країнах. Проаналізовано подібності та відмінності в хемічному складі та властивостях стопів. Розглянуто технології лиття й адитивного виробництва для виготовлення деталів з алюмінійових стопів. Показано вплив процесів структуроутворення під час затвердіння стопів на їхній фазовий склад і механічні властивості. Розглянуто різні леґувальні елементи та проаналізовано вплив їх на мікроструктуру та властивості. Рекомендовано обмеження вмісту кожного леґувального елемента й основні технологічні особливості топлення стопів. Також обговорено методи модифікування стопів. Показано вплив різних модифікувальних елементів на морфологію загальної структури та фази зміцнення. В окремому розділі статті наведено огляд різних термічних оброблень литих алюмінійових стопів. Ці стопи є дуже чутливими щодо термічного впливу. Тому вибір відповідних умов термічного оброблення є ключовим для значного підвищення міцности (іноді в 1,5–2,0 рази) шляхом утворення додаткових структурних (фазових) складових. Зокрема, визначено процедури оброблення деталів, що використовуються в екстремальних умовах (високі температури понад 300 °C, аґресивні середовища тощо, як в авіаційній або аерокосмічній промисловостях). Перераховано найпоширеніші інтерметалідні фази в алюмінійових стопах; обговорюється вплив кожної з цих фаз на властивості. Побудовано порівняльну діяграму, яка показує механічні властивості (міцність і пластичність) стопів, що зазвичай використовуються, та тих, що розробляються (експериментальні стопи). Дані, наведені на цій діяграмі, поєднують результати багаторічних досліджень, проведених дослідниками з різних країн, які були опубліковані у провідних наукових журналах. Також представлено дані щодо міцности за підвищених температур, розглянуто механічні властивості за високих температур (до 450 °C) і за тривалого впливу екстремальних умов. Визначено актуальні науково-технологічні проблеми, над якими зараз працюють фахівці з лиття алюмінію.

Ключові слова: алюмінійові ливарні стопи, леґування, термічне оброблення, механічні властивості, структуроутворення, утилізація.

DOI: https://doi.org/10.15407/ufm.27.03.***

Citation: R.V. Liutyi, I.Ya. Petryk, D.V. Ivanchenko, М.М. Yamshіnskij, I.V. Lukianenko, I.G. Byba, B.V. Kyvhylo, S.V. Petrychenko, V.V. Kovalenko, D.S. Leonov, and М.Yu. Barabash, Cast Aluminium Alloys as Competitive Modern Structural Materials: Chemical Composition, Properties, and Applications, Progress in Physics of Metals, 27, No. 3: ***–*** (2026)


Цитована література   
  1. Doru M. Stefanescu and Roxana Ruxanda, Solidification Structure of Aluminum Alloys. In book: ASM Handbook — Metallography and Microstructures. Chapter: Solidification Structure of Aluminum Alloys (ASM International: 2004), vol. 9, pp. 107–115; https://doi.org/10.13140/RG.2.1.2892.0169
  2. Ghulam Asghar, Liming Peng, Penghuai Fu, Lingyang Yuan, and Yue Liu, Role of Mg2Si precipitates size in determining the ductility of A357 cast alloy, Materials & Design, 186: 108280 (2020); https://doi.org/10.1016/j.matdes.2019.108280
  3. Tolga Dursun and Costas Soutis, Recent developments in advanced aircraft aluminium alloys, Materials & Design (1980–2015), 56: 862 (2014); https://doi.org/10.1016/j.matdes.2013.12.002
  4. Pan Deng, Wenfeng Mo, Zuoqiong Ouyang, Chenglu Tang, Binghui Luo, and Zhenhai Bai, Mechanical properties and corrosion behaviors of (Sc, Zr) modified Al–Cu–Mg alloy, Materials Characterization, 196: 112619 (2023); https://doi.org/10.1016/j.matchar.2022.112619
  5. S. Mondol, S. K. Makineni, S. Kumar, and K. Chattopadhyay, Enhancement of high temperature strength of 2219 alloys through small additions of Nb and Zr and a novel heat treatment, Metall. Mater. Trans. A, 49: 3047 (2018); https://doi.org/10.1007/s11661-018-4614-3
  6. S. Mondol, S. Kashyap, S. Kumar, and K. Chattopadhyay, Improvement of high temperature strength of 2219 alloy by Sc and Zr addition through a novel three-stage heat treatment route, Materials Science and Engineering: A, 732: 157 (2018); https://doi.org/10.1016/j.msea.2018.07.003
  7. S. Mondol, T. Alam, R. Banerjee, S. Kumar, and K. Chattopadhyay, Development of a high temperature high strength Al alloy by addition of small amounts of Sc and Mg to 2219 alloy, Materials Science and Engineering: A, 687: 221 (2017); https://doi.org/10.1016/j.msea.2017.01.037
  8. Brian K. Milligan, Shibayan Roy, Charles S. Hawkins, Lawrence F. Allard, and Amit Shyam, Impact of microstructural stability on the creep behavior of cast Al–Cu alloys, Materials Science and Engineering: A, 772: 138697 (2020); https://doi.org/10.1016/j.msea.2019.138697
  9. Qing-bo Yang, Yan-jun Deng, Mou Yang, Zhi-qing Zhang, Wei-guo Li, Qing Liu, Effect of Al3Zr particles on hot-compression behavior and processing map for Al–Cu–Li based alloys at elevated temperatures, Transactions of Nonferrous Metals Society of China, 30, Iss. 4: 872 (2020); https://doi.org/10.1016/S1003-6326(20)65261-X
  10. N. S. Barekar and B. K. Dhindaw, Twin-roll casting of aluminum alloys — An overview, Materials and Manufacturing Processes, 29: Iss. 6: 651 (2014); https://doi.org/10.1080/10426914.2014.912307
  11. Ali Alhamidi and Zenji Horita, Grain refinement and high strain rate superplasticity in alumunium 2024 alloy processed by high-pressure torsion, Materials Science and Engineering: A, 622: 139 (2015); https://doi.org/10.1016/j.msea.2014.11.009
  12. Tolga Dursun and Costas Soutis, Recent developments in advanced aircraft aluminium alloys, Materials & Design (1980–2015), 56: 862 (2014); https://doi.org/10.1016/j.matdes.2013.12.002
  13. Nesma T. Aboulkhair, Marco Simonelli, Luke Parry, Ian Ashcroft, Christopher Tuck, and Richard Hague, 3D printing of aluminium alloys: additive manufacturing of aluminium alloys using selective laser melting, Progress in Materials Science, 106: 100678 (2019); https://doi.org/10.1016/j.pmatsci.2019.100578
  14. Zhixiu Wang, Fan Zhu, Kai Zheng, Jun Jia, Yulong Wei, Hai Li, Lanping Huang, and Ziqiao Zheng, Effect of the thickness reduction on intergranular corrosion in an under-aged Al–Mg–Si–Cu alloy during cold-rolling, Corrosion Science, 142: 201 (2018); https://doi.org/10.1016/j.corsci.2018.07.018
  15. P.P. Ma, C.H. Liu, C.L. Wu, L.M. Liu, and J.H. Chen, Mechanical properties enhanced by deformation-modified precipitation of -phase approximants in an Al–Cu alloy, Materials Science and Engineering: A, 676: 138 (2016); https://doi.org/10.1016/j.msea.2016.08.068
  16. Bo-Chin Huang and Fei-Yi Hung, Effect of high temperature and thermal cycle of 4043 Al alloy manufactured through continuous casting direct rolling, Materials, 16: 7176 (2023); https://doi.org/10.3390/ma16227176
  17. A.S. Kocheshkov, R.V. Liutyi, and M.M. Yamshynskyi, Spetsialni ta Osob-lyvi Sposoby Lyttya [Special and special casting methods] (Kyiv: KPI im. Ihoria Sikorskoho: 2026) (in Ukrainian).
  18. Matthias Bünck, Todor Stoyanov, Jan Schievenbusch, Heiner Michels, and Alexander Gußfeld, Titanium aluminide casting technology development, JOM, 69: 2565 (2017); https://doi.org/10.1007/s11837-017-2534-0
  19. S.I. Repiakh, Tekhnolohichni Osnovy Lyttia za Vytopliuvanymy Modeliamy [Technological basics of investment casting] (Dnipro: Lira: 2006) (in Ukrainian).
  20. P.B. Kaliuzhnyi, V.S. Doroshenko, O.V. Neima, Lyttya za kombinovanymy polimernymy modeliamy, shcho hazyfikuyutsya [Casting using combined polymer models that gasify], Protsesy Lyttya, 152, No. 2: 49 (2023) (in Ukrainian); https://doi.org/10.15407/plit2023.02.049
  21. Rostyslav Liutyi, Dmytro Ivanchenko, Andrii Velychkovych, Andriy Andrusyak, Mykhailo Yamshinskij, and Ivan Petry, Analytical study of temperature fields in aluminum alloy castings during solidification in sand and metal molds, Materials, 19, Iss. 9: 1849 (2026); https://doi.org/10.3390/ma19091849
  22. N. Rathinam, R. Dhinakaran, and E. Sharath, Optimizing process parameters to reduce blowholes in high pressure die casting using Taguchi methodology, Materials Today: Proceedings, 38, Pt. 5: 2871 (2021); https://doi.org/10.1016/j.matpr.2020.09.139
  23. K. Ch. Apparaoa and Anil Kumar Birrub, Optimization of die casting process based on Taguchi approach, Materials Today: Proceedings, 4, Iss. 2, Pt. A: 1852 (2017); https://doi.org/10.1016/j.matpr.2017.02.029
  24. Ildiko Peter and Mario Rosso, Light Alloys — From Traditional to Innovative Technologies. New Trends in Alloy Development, Characterization and Application (Ed. Zaki Ahmad) (InTech: 2015); doi:10.5772/60769
  25. А.Yu. Sezonenko, М.М. Petryshyn, А.А. Кolesnichenko, R.V. Lytvyn І.V. Lukianenko, Ie.G. Byba, М.М. Yamshinskij, and М.Yu. Barabash, Features of structure and properties of Al–Si–Cu alloy produced by pressure casting, Results in Materials, 21: 100539 (2024); https://doi.org/10.1016/j.rinma.2024.100539
  26. M.M. Petryshyn, A.Yu. Sezonenko, M.M. Yamshinskij, Ie.G. Byba, I.V. Lukianenko, D.S. Leonov, A.A. Kolesnichenko, R.V. Lytvyn, and M.Yu. Barabash, Vplyv nadlyshkovoho tysku v protsesi krystalizatsii na strukturu ta vlastyvosti splavu systemy Al–Si–Cu dlya aviatsiynoi tekhniky [Injection of excess pressure during the crystallization process on the structure and power of the alloy of the Al–Si–Cu system for aviation technology], Metallofiz. Noveishie Tekhnol., 46, Iss. 4: 325 (2024) (in Ukrainian); https://doi.org/10.15407/mfint.46.04.0325
  27. Kang Du, Qiang Zhu, Daquan Li, and Fan Zhang, Study of formation mechanism of incipient melting in thixo-cast Al–Si–Cu–Mg alloys, Materials Characterization, 106: 134 (2015); https://doi.org/10.1016/j.matchar.2015.05.035
  28. S.V. Petrychenko, O.A. Narizhnyi, M.M. Yamshynskyi, Ie.G. Byba, A.V. Minitskyi, M.Yu. Barabash, B.V. Kyvhylo, and I.V. Lukianenko, Pereroblennya aliuminiyevoho brukhtu z viyskovoho sektora: ekolohichni i tekhnolohichni aspekty [Recycling of aluminum scrap from the military sector: environmental and technological aspects], Protsesy Lyttya, 3, No. 161: 82 (2025) (in Ukrainian); https://doi.org/10.15407/plit2025.03.082
  29. S.V. Petrychenko, V.V. Kovalenko, Ye.H. Byba, A.V. Minitskyi, I.V. Lukianenko, N.V. Minitska, M.M. Yamshynskyi, M.Iu. Barabash, Formuvannya dribnodyspersnoi struktury vtorynnykh aliuminiyevykh splaviv shlyakhom rafinuvannya ta korektsii khimichnoho skladu [Formation of a fine-dispersed structure of secondary aluminum alloys by refining and correction of chemical composition], Naukovo-Tekhnichnyi Zhurnal ‘Metaloznavstvo ta Obrobka Metaliv’, 31, No. 116: 24 (2025) (in Ukrainian); https://doi.org/10.15407/mom2025.04.024
  30. S.V. Petrychenko, V.V. Kovalenko, M.M. Yamshynskyi, Ye.G. Byba, I.V. Lukianenko, A.V. Minitskyi, B.V. Kyvhylo, and M.Yu. Barabash, Optymizatsiya skladu flyusu NaCl–KCl dlya pidvyshchennya yakosti ochyshchennya aliuminiyevykh splaviv [Optimization of the composition of NaCl–KCl flux to improve the cleaning quality of aluminum alloys], Metal ta Lyttia Ukrainy, 33, Nos. 3–4: 342 (2025) (in Ukrainian); https://doi.org/10.15407/steelcast2025.03-04.076
  31. Tomasz Trzepieciński, Sherwan Mohammed Najm, Tomaž Pepelnjak, Kamel Bensaid, and Marcin Szpunar, Incremental sheet forming of metal-based composites used in aviation and automotive applications, J. Compos. Sci., 6, Iss. 10: 295 (2022); https://doi.org/10.3390/jcs6100295
  32. Roberto Montanari, Alessandra Palombi, Maria Richetta, and Alessandra Varone, Additive manufacturing of aluminum alloys for aeronautic applications: advantages and problems, Metals, 13: 716 (2023); https://doi.org/10.3390/met13040716
  33. Rong Xu, Ruidi Li, Tiechui Yuan, Pengda Niu, Minbo Wang, and Zehuan Lin, Microstructure, metallurgical defects and hardness of Al–Cu–Mg–Li–Zr alloy additively manufactured by selective laser melting, Journal of Alloys and Compounds, 835: 155372 (2020); https://doi.org/10.1016/j.jallcom.2020.155372
  34. Z.Q. Zheng, B. Cai, T. Zhai, and S.C. Li, The behavior of fatigue crack initiation and propagation in AA2524–T34 alloy, Materials Science and Engineering: A, 528, Iss. 4–5: 2017 (2011); https://doi.org/10.1016/j.msea.2010.10.085
  35. A.I. Belyaev, O.A. Romanova, O.S. Bochvar, N.I. Kolobnev, A.A. Kolpachev, L.A. Kostyukov, K.S. Pokhodaev, O.G. Senatorova, R.R. Romanova, E.A. Tkachenko, and I.N. Fridlyander, Metallovedenie Alyuminiya i Ego Splavov. Spravochnoye Rukovodstvo [Metallurgy of aluminum and its alloys: a reference guide] (Moskva: Metallurgiya: 1983) (in Russian).
  36. Jovid Rakhmonov, Kun Liu, Lei Pan, Francis Breton, and X.-Grant Chen, Enhanced mechanical properties of high-temperature-resistant Al–Cu cast alloy by microalloying with Mg, Journal of Alloys and Compounds, 827: 154305 (2020); https://doi.org/10.1016/j.jallcom.2020.154305
  37. Shin Sang-Soo, Lim Kyoung-Mook, and Park Ik-Min, Characteristics and microstructure of newly designed Al–Zn-based alloys for the die-casting process, Journal of Alloys and Compounds, 671: 517 (2016); https://doi.org/10.1016/j.jallcom.2016.02.127
  38. Y.H. Gao, J. Kuang, G. Liu, and J. Sun, Effect of minor Sc and Fe co-addition on the microstructure and mechanical properties of Al–Cu alloys during homogenization treatment, Materials Science and Engineering: A, 746: 11 (2019); https://doi.org/10.1016/j.msea.2018.12.099
  39. Yanlin Pan, Di Zhang, Haoran Liu, Linzhong Zhuang, and Jishan Zhang, Precipitation hardening and intergranular corrosion behavior of novel Al–Mg–Zn(–Cu) alloys, Journal of Alloys and Compounds, 853: 157199 (2021); https://doi.org/10.1016/j.jallcom.2020.157199
  40. Jingxiao Li, Xiaofang Yang, Shihua Xiang, Yongfa Zhang, Jie Shi, Youcai Qiu, and Robert Edward Sanders, Effects of Sc and Zr Addition on Microstructure and Mechanical Properties of AA5182, Materials, 14, Iss. 16: 4753 (2021); https://doi.org/10.3390/ma14164753
  41. Funda Gül Koç, Erdem Karakulak, Ridvan Yamanoğlu, and M. Zeren, Mechanical properties of Al–Ni cast alloys, METAL 2014 — 23rd International Conference on Metallurgy and Materials. Conference Proceedings (May 21–23, 2014, Brno, Czech Republic), p. 1283–1287; https://www.researchgate.net/publication/286213763_Mechanical_properties_of_Al-Ni_cast_alloys
  42. Thomas Dorin, Mahendra Ramajayam, Justin Lamb, and Timothy Langan, Effect of Sc and Zr additions on the microstructure/strength of Al–Cu binary alloys, Materials Science and Engineering: A, 707: 58 (2017); https://doi.org/10.1016/j.msea.2017.09.032
  43. Thomas Dorin, Mahendra Ramajayam, Alireza Vahid, and Timothy Langan, Chapter 12 — Aluminium Scandium Alloys. Fundamentals of Aluminium Metallurgy (Woodhead Publishing Series in Metals and Surface Engineering) (Ed. Roger N. Lumle) (Elsevier Ltd.: 2018), p. 439–494; https://doi.org/10.1016/B978-0-08-102063-0.00012-6
  44. Sumit Bahl, Lianghua Xiong, Lawrence F. Allard, Richard A. Michi, Jonathan D. Poplawsky, Andrew Chihpin Chuang, Dileep Singh, Thomas R. Watkins, Dongwon Shin, J. Allen Haynes, and Amit Shyam, Aging behavior and strengthening mechanisms of coarsening resistant metastable  precipitates inan Al–Cu alloy, Materials and Design, 198: 109378 (2021); https://doi.org/10.1016/j.matdes.2020.109378
  45. Farnaz Yavari, Ahmed Y. Algendy, Mousa Javidani, Lei Ray Pan, and X.-Grant Chen, Effects of Ni Content and Alloying Elements on Electrical Conductivity, Mechanical Properties, and Hot Tearing Susceptibility of Al–Ni-Based Alloys, Engineering Proceedings, 43, Iss. 1: 3 (2023); https://doi.org/10.3390/engproc2023043003
  46. Xiang Su, Hongjie Qu, Yuan Lei, Rui Hou, Yuede Cao, Suniya Siddique, Zhixiang Qi, Guoyan Shen, and Xueyi Fan, Influence of Ni on the Microstructures and Mechanical Properties of Heat-Treated Al–Cu–Ce–Mn–Zr Alloys, Crystals, 13, Iss. 3: 380 (2023); https://doi.org/10.3390/cryst13030380
  47. Qing Liu, Rui-hua Zhu, Jin-feng Li, Yong-lai Chen, Xu-hu Zhang, Long Zhang, and Zi-qiao Zheng, Microstructural evolution of Mg, Ag and Zn micro-alloyed Al–Cu–Li alloy during homogenization, Transactions of Nonferrous Metals Society of China, 26, Iss. 3: 607 (2016); https://doi.org/10.1016/S1003-6326(16)64149-3
  48. Jingguang Du, Yucheng Yang, Yaojia Ren, Hong Wu, Quan Shan, Xiaolan Wu, Yalin Lu, Ian Baker, A crack-free Ti-modified Al–Cu alloy processed by in-situ alloying laser powder bed fusion: Tribological behaviors and mechanical properties, Journal of Alloys and Compounds, 960: 170549 (2023); https://doi.org/10.1016/j.jallcom.2023.170549
  49. Qian Wang, Meng Wang, Xueping Li, Yufan Shen, Shuai Guo, Jiabao Guo, Xin Lin, and Weidong Huang, Ti modification mechanisms and effects of processing parameters on defect control and equiaxed grain formation in laser powder bed fused Al–Li–Cu alloy, Journal of Materials Processing Technology, 343: 118997 (2025); https://doi.org/10.1016/j.jmatprotec.2025.118997
  50. Qiyang Tan, Jingqi Zhang, Qiang Sun, Zhiqi Fan, Gan Li, Yu Yin, Yingang Liu, and Ming-Xing Zhang, Inoculation treatment of an additively manufactured 2024 aluminium alloy with titanium nanoparticles, Acta Mater., 196: 1 (2020); https://doi.org/10.1016/j.actamat.2020.06.026
  51. Marek Matejka, Dana Bolibruchová, and Martina Sýkorová, Effect of Ti addition on the hot-tearing susceptibility of the AlSi5Cu2Mg Alloy, Metals, 14: 703 (2024); https://doi.org/10.3390/met14060703
  52. Kuishen Hu, Chunming Zou, Hongwei Wang, and Zunjie Wei, Influence of Ti elements on the evolution of microstructure, mechanical properties and thermal stability of Al–Cu alloy, J. Alloys Compd., 952: 169860 (2023); https://doi.org/10.1016/j.jallcom.2023.169860
  53. Mingqi Zhao, Yuan Xing, Zhihong Jia, Qing Liu, and Xiaozhi Wu, Effects of heating rate on the hardness and microstructure of Al–Cu and Al–Cu–Zr–Ti–V alloys, J. Alloys Compd., 686: 312 (2016); https://doi.org/10.1016/j.jallcom.2016.06.063
  54. Feng Wang, Dmitry Eskin, Thomas Connolley, and Jiawei Mi, Effect of ultrasonic melt treatment on the refinement of primary Al3Ti intermetallic in an Al–0.4Ti alloy, J. Cryst. Growth, 435: 24 (2016); https://doi.org/10.1016/j.jcrysgro.2015.11.034
  55. X.Z. Chen, Y.H. Gao, D.H. Liu, X. Wu, X.C. Liu, Competition of heterogeneous Cu-related precipitation on Al3(Zr, Ti) and Cd-rich nuclei in an Al–Cu–Mn–Zr–Ti–Cd alloy, Scripta Mater., 279: 117301 (2026); https://doi.org/10.1016/j.scriptamat.2026.117301
  56. Jonathan D. Poplawsky, Brian K. Milligan, Lawrence F. Allard, Dongwon Shin, Patrick Shower, Matthew F. Chisholm, and Amit Shyam, The synergistic role of Mn and Zr/Ti in producing θ′/L12 co-precipitates in Al–Cu alloys, Acta Mater., 194: 577 (2020); https://doi.org/10.1016/j.actamat.2020.05.043
  57. Z. Fan, Y. Wang, Y. Zhang, T. Qin, X.R. Zhou, G.E. Thompson, T. Pennycook, and T. Hashimoto, Grain refining mechanism in the Al/Al–Ti–B system, Acta Mater., 84: 292 (2015); https://doi.org/10.1016/j.actamat.2014.10.055
  58. Vadim S. Zolotorevsky, Nikolai A. Belov, and Michael V. Glazoff, Casting Aluminum Alloys (Amsterdam: Elsevier: 2007); https://doi.org/10.1016/B978-0-08-045370-5.X5001-9
  59. Puthiyavalappil Rasin, Ashwathi A.V., Sabeel M. Basheer, Jebiti Haribabu, Juan F. Santibanez, Claudio Allard Garrote, Arunachalam Arulraj, and Ramalinga Viswanathan Mangalaraja, Exposure to cadmium and its impacts on human health: A short review, Journal of Hazardous Materials Advances, 17: 100608 (2025); https://doi.org/10.1016/j.hazadv.2025.100608
  60. O.M. Smirnov, A.L. Berezina, T.O. Monastyrska, V.M. Fikssen, O.V. Yashchenko, Yu.P. Skorobagatko, M.S. Goryuk, A.Yu. Semenko, E.O. Karpukhin, and O.D. Rud, Features of alloying and heat treatment of high-strength casting aluminium–copper alloys, Metallofiz. Noveishie Tekhnol., 46, No. 6: 559 (2024); https://doi.org/10.15407/mfint.46.06.0559
  61. Changlin Li, Xiwu Li, Yongan Zhang, Kai Wen, Lizhen Yan, Ying Li, Yanan Li, Mingyang Yu, Guanjun Gao, Hongwei Yan, Zhihui Li, and Baiqing Xiong, Effect of Cu/Li Ratio on Mechanical Properties and Corrosion Behavior of Sc-Containing Al–Cu–Li Alloys, Materials, 18, Iss. 10: 2254 (2025); https://doi.org/10.3390/ma18102254
  62. C.H. Wu, H. Li, T.J. Bian, C. Lei, and L.W. Zhang, Natural aging behaviors of Al–Cu–Li alloy: PLC effect, properties and microstructure evolution, Materials Characterization, 184: 111694 (2022); https://doi.org/10.1016/j.matchar.2021.111694
  63. Xiaoyu Huang, Tianlin Huang, Oleg V. Mishin, YueYue Zhu, Guilin Wu, and Xiaoxu Huang, Achieving superior high-temperature strength in nanostructured Al–Cu–Mn alloy with Sc addition, Materials Research Letters, 14, Iss. 2: 186 (2026); https://doi.org/10.1080/21663831.2025.2611736
  64. D.V. Ivanchenko and M.M. Yamshynskyi, Tekhnolohichni osoblyvosti vyhotovlennya splavu AK7ch, zmitsnenoho tsyrkoniyem, uvedenym iz tetraftorydu tsyrkoniyu [Technological features of the production of AK7ch alloy strengthened with zirconium introduced from zirconium tetrafluoride], Protsesy Lyttya, 2, No. 152: 16 (2023) (in Ukrainian); https://doi.org/10.15407/plit2023.02.016
  65. D.V. Ivanchenko and M.M. Yamshynskyi, Tetraftoryd tsyrkoniyu yak zmitsnyuvach alyuminiyu ta splaviv na yoho osnovi [Zirconium tetrafluoride as a hardener for aluminum and alloys based on it], Protsesy Lyttya, 2, No. 156: 3 (2024) (in Ukrainian); https://doi.org/10.15407/plit2024.02.003
  66. D.V. Ivanchenko, M.M. Yamshynskyi, I.Ia. Petryk, I.V. Lukianenko, Ye.P. Chvertko, B.V. Kyvhylo, R.V. Liutyi, Ye.G. Byba, and I.A. Vladymyrskyi, Zmina struktury ta mekhanichnykh vlastyvostei lyvarnoho splavu AM5, zmitsnenoho Zr [Changes in the structure and mechanical properties of the AM5 casting alloy strengthened with Zr], Protsesy Lyttya, 4, No. 162: 32 (2025) (in Ukrainian); https://doi.org/10.15407/plit2025.04.032
  67. F. Liu, Z.Y. Liu, G.Y. He, and L.N. Ou, Dislocation ordering and texture strengthening of naturally aged Al–Cu–Mg alloy, Journal of Materials Science & Technology, 118: 1 (2022); https://doi.org/10.1016/j.jmst.2021.12.011
  68. Keith E. Knipling, Richard A. Karnesky, Constance P. Lee, David C. Dunand, and David N. Seidman, Precipitation evolution in Al–0.1Sc, Al–0.1Zr and Al–0.1Sc–0.1Zr (at.%) alloys during isochronal aging, Acta Materialia, 58, No. 15: 5184 (2010); https://doi.org/10.1016/j.actamat.2010.05.054
  69. Miao Yu, Bing Zhu, Ning Li, Haiyang Zheng, Yang Lu, and Xiaopeng Yu, Research on microstructure and mechanical properties at elevated temperature of Al–Mg–Si–Sc–Zr alloy strengthened by Al3(Sc, Zr) nanoprecipitates, Journal of Alloys and Compounds, 985: 174050 (2024); https://doi.org/10.1016/j.jallcom.2024.174050
  70. Min Zha, Teng Tian, Hai-Long Jia, Hong-Min Zhang, and Hui-Yuan Wang, Sc/Zr ratio-dependent mechanisms of strength evolution and microstructural thermal stability of multi-scale hetero-structured Al–Mg–Sc–Zr alloys, Journal of Materials Science & Technology, 140: 67 (2023); https://doi.org/10.1016/j.jmst.2022.09.009
  71. Keith E. Knipling, David C. Dunand, and David N. Seidman, Precipitation evolution in Al–Zr and Al–Zr–Ti alloys during isothermal aging at 375–425 °C, Acta Materialia, 56, Iss. 1: 114 (2008); https://doi.org/10.1016/j.actamat.2007.09.004
  72. Peng Hu, Kun Liu, Lei Pan, and X.-Grant Chen, Impact of combined Zr, Ti, and V additions on the microstructure, mechanical properties, and thermomechanical fatigue behavior of Al–Cu cast alloys, J. Manuf. Mater. Process, 8: 250 (2024); https://doi.org/10.3390/jmmp8060250
  73. Teng-teng Sun, Ji-wei Geng, Ze-yu Bian, Yi Wu, Ming-liang Wang, Dong Chen, Nai-heng Ma, and Hao-wei Wang, Enhanced thermal stability and mechanical properties of high-temperature resistant Al−Cu alloy with Zr and Mn micro-alloying, Transactions of Nonferrous Metals Society of China, 32, Iss. 1: 64 (2022); https://doi.org/10.1016/S1003-6326(21)65778-3
  74. Zhen Li, Zhan Zhang, and X.-Grant Chen, Improvement in the mechanical properties and creep resistance of Al–Mn–Mg 3004 alloy with Sc and Zr addition, Materials Science and Engineering: A, 729: 196 (2018); https://doi.org/10.1016/j.msea.2018.05.055
  75. J.F. Nie and B.C. Muddle, Strengthening of an Al–Cu–Sn alloy by deformation-resistant precipitate plates, Acta Materialia, 56: 3490 (2008); https://doi.org/10.1016/j.actamat.2008.03.028
  76. Andong Du, Anders E. W. Jarfors, Jinchuan Zheng, Kaikun Wang, and Gegang Yu, The influence of La and Ce on microstructure and mechanical properties of an Al–Si–Cu–Mg–Fe alloy at high temperature, Metals, 11: 384 (2021); https://doi.org/10.3390/met11030384
  77. Frank Czerwinski, Cerium in aluminum alloys, Journal of Materials Science, 55: 24 (2020); https://doi.org/10.1007/s10853-019-03892-z
  78. Kazuhiro Nogita, Stuart D. McDonald, and Arne K. Dahle, Eutectic Modification of Al-Si Alloys with Rare Earth Metals, Materials Transactions, 45, No. 2: 323 (2004); https://doi.org/10.2320/matertrans.45.323
  79. Keith E Knipling, David C Dunand, and David N Seidman, Criteria for developing castable, creep-resistant aluminum-based alloys — A review, Zeitschrift für Metallkunde, 97: 246 (2006); doi:10.3139/146.101249
  80. K. Ma, E.M. Elgallad, Z.X. Chen, B.L. Xiao, and X.-Grant Chen, Improving the elevated-temperature mechanical properties of AA3004 hot-rolled sheets by microalloying with Mo and optimizing the process route, Journal of Materials Research and Technology, 19: 4489 (2022); https://doi.org/10.1016/j.jmrt.2022.06.171
  81. A.N. Stepanchuk, I.I. Bilyk, and P.A. Boyko, Tehnologiya Poroshkovoy Metallurgii [Powder metallurgy technology] (Kiev: Vishha Shkola: 1989) (in Russian).
  82. A.R. Andrievskij and I.I. Spivak, Prochnost’ tugoplavkih soedineniy i materialov na ikh osnove: Spravochnik [Strength of refractory compounds and materials based on them: Handbook] (Chelyabinsk: Metallurgiya: 1989) (in Russian).
  83. D.F. Chernega, A.P. Dyatlov, and V.G. Mogilatenko, Modifitsirovanie Alyuminievykh Splavov Ul’tradispersnymi Poroshkami Nitridov. IV Respublikanskaya Nauchno-Tekhnicheskaya Konferentsiya ‘Mekhanizatsiya i Povyshenie Ehffektivnosti Tekhnologicheskikh Protsessov Proizvodstva Otlivok Metallurgicheskogo Oborudovaniya’ [Modification of aluminum alloys with ultrafine nitride powders. IV Republican Scientific and Technical Conference ‘Mechanization and Efficiency Improvement of Technological Processes for the Production of Metallurgical Equipment Castings’] (Dnepropetrovsk: 1986), p. 11 (in Russian).
  84. V.G. Mogilatenko, D.F. Chernega, and Yu.P. Skrinskiy, Lityye Kompozitsii Na Osnove Intermetallida s Dispersnymi Nitridnymi Chastitsami. Novyye Tekhnologii i Marketing v Liteynom Proizvodstve [Casting composites based on intermetallic compounds with dispersed nitride particles. New technologies and marketing in foundry production] (Kiev: NTUU ‘KPI’: 1995), p. 44–45 (in Russian).
  85. D.F. Chernega, A.P. Dyatlov, I.M. Guriya, and V.M. Tkach, Vliyanie ul’tradispersnykh chastits na velichinu zerna pervichnogo kremniya zaehvtekticheskikh siluminov. Sovremennyye tekhnologicheskie protsessy v liteynom proizvodstve [The influence of ultrafine particles on the grain size of primary silicon in hypereutectic silumins. Modern technological processes in foundry production] (Kiev: Znanie: 1991), p. 3 (in Russian).
  86. Yu. P. Skorobagat’ko, Modifitsirovanie zaehvtekticheskikh alyuminievykh splavov s primeneniem aktivnykh dobavok [Modifying of hypereutectic aluminium alloys with the use of active additions], Metall i Lit’e Ukrainy, 9: 19 (2009) (in Russian); https://nasplib.isofts.kiev.ua/server/api/core/bitstreams/29973035-4d5f-4e2a-bdb0-cdeddef6c837/content
  87. Yu-Yang Gao, Feng Qiu, Qing-Long Zhao, and Qi-Chuan Jiang, A new approach for improving the elevated-temperature strength and ductility of Al–Cu–Mg–Si alloys with minor amounts of dual-phased submicron/nanosized TiB2–TiC particles, Materials Science and Engineering A, 764: 138266 (2019); https://doi.org/10.1016/j.msea.2019.138266
  88. A.A. Shhereckiy, Lityye Kompozitsionnyye Materialy na Osnove Alyuminiya s Dispersnymi Chastitsami. Sovremennyye Materialy i Tekhnologii v Metallurgii i Mashinostroyenii [Cast composite materials based on these materials are observed with dispersed particles. Modern materials and technologies in metallurgy and mechanical engineering] (Kiev: 2007), p. 158–159 (in Russian).
  89. James C Williams and Edgar A Starke Jr., Progress in structural materials for aerospace systems, Acta Materialia, 51, Iss. 19: 5775 (2003); doi:10.1016/j.actamat.2003.08.023
  90. F. Casarotto, A.J. Franke, and R. Franke, 6 - High-pressure die-cast (HPDC) aluminium alloys for automotive applications, Advanced Materials in Automotive Engineering, 2012: 1099 (2012); https://doi.org/10.1533/9780857095466.109
  91. Shuang-Shuang Li, Xin Yue, Qing-Yuan Li, He-Li Peng, Bai-Xin Dong, Tian-Shu Liu, Hong-Yu Yang, Jun Fan, Shi-Li Shu, Feng Qiu, and Qi-Chuan Jiang, Development and applications of aluminum alloys for aerospace industry, Journal of Materials Research and Technology, 27: 944 (2023); doi:10.1016/j.jmrt.2023.09.274
  92. A. Rodríguez-Veiga, B. Bellón, I. Papadimitriou, G. Esteban-Manzanares, I. Sabirov, and J. Llorca, A multidisciplinary approach to study precipitation kinetics and hardening in an Al–4Cu (wt.%) alloy, Journal of Alloys and Compounds, 757: 504 (2018); doi:10.1016/j.jallcom.2018.04.284
  93. Iuliana Lichioiu, Ildiko Peter, Bela Varga, and Mario Rosso, Preparation and structural characterization of rapidly solidified Al–Cu alloys, Journal of Materials Science & Technology, 30, Iss. 4: 394 (2014); doi:10.1016/j.jmst.2013.12.001
  94. A. Shyam, S. Roy, D. Shin, J.D. Poplawsky, L.F. Allard, Y. Yamamoto, J.R. Morris, B. Mazumder, J.C. Idrobo, A. Rodriguez, T.R. Watkins, and J.A. Haynes, Elevated temperature microstructural stability in cast AlCuMnZr alloys through solute segregation, Materials Science and Engineering: A, 765: 138279 (2019); https://doi.org/10.1016/j.msea.2019.138279
  95. A.Yu. Sezonenko, M.M. Yamshynskyi, Ye.G. Byba, I.V. Lukianenko, Ya.I. Yevych, D.S. Leonov, A.V. Minitskyi, R.V. Lytvyn, and M.Yu. Barabash, Struktura ta vlastyvosti aviatsiynoho mikrolegovanoho stopu systemy Al–Cu, otrymanoho metodom lyttya pid tyskom [Structure and properties of an aviation microalloyed alloy of the Al–Cu system obtained by injection moulding], Metallofiz. Noveishie Tekhnol., 47, No. 10: 1083 (2025) (in Ukrainian); https://doi.org/10.15407/mfint.47.10.1083
  96. Zhaorui Zhang, Yue Li, Hongxiang Li, Di Zhang, and Jishan Zhang, Effect of high Cu concentration on the mechanical property and precipitation behavior of Al–Mg–Zn–(Cu) crossover alloys, Journal of Materials Research and Technology, 20: 4585 (2022); https://doi.org/10.1016/j.jmrt.2022.08.171
  97. Y.H. Gao, L.F. Cao, J. Kuang, J.Y. Zhang, G. Liu, and J. Sun, Assembling dual precipitates to improve high-temperature resistance of multi-microalloyed Al–Cu alloys, Journal of Alloys and Compounds, 822: 153629 (2020); https://doi.org/10.1016/j.jallcom.2019.153629
  98. S.K. Kairy, B. Rouxel, J. Dumbre, J. Lamb, T.J. Langan, T. Dorin, and N. Birbilis, Simultaneous improvement in corrosion resistance and hardness of a model 2xxx series Al–Cu alloy with the microstructural variation caused by Sc and Zr additions, Corrosion Science, 158: 108095 (2019); https://doi.org/10.1016/j.corsci.2019.108095
  99. Naoki Takata, Masato Ishihara, Asuka Suzuki, and Makoto Kobashi, Microstructure and strength of a novel heat-resistant aluminum alloy strengthened by T-Al6Mg11Zn11 phase at elevated temperatures, Materials Science and Engineering: A, 739: 62 (2019); https://doi.org/10.1016/j.msea.2018.10.034
  100. Hua-Ping Tang, Qu-Dong Wang, Colin Luo, Chuan Lei, Tian-Wen Liu, Zhong-Yang Li, Hai-Yan Jiang, Wen-Jiang Ding, Jian Fang, and Jian-Wei Zhang, Effects of aging treatment on the precipitation behaviors and mechanical properties of Al–5.0Mg–3.0Zn–1.0Cu cast alloys, Journal of Alloys and Compounds, 842: 155707 (2020); https://doi.org/10.1016/j.jallcom.2020.155707
  101. Jinliang Zhang, Bo Song, Qingsong Wei, Dave Bourell, and Yusheng Shi, A Review of selective laser melting of aluminum alloys: processing, microstructure, property and developing trends, Journal of Materials Science and Technology, 35, Iss. 2: 270 (2018); https://doi.org/10.1016/j.jmst.2018.09.004
  102. Y. Nasedkina, X. Sauvage, E.V. Bobruk, M.Yu. Murashkin, R.Z. Valiev, and N.A. Enikeev, Mechanisms of precipitation induced by large strains in the Al–Cu system, Journal of Alloys and Compounds, 710: 736 (2017); https://doi.org/10.1016/j.jallcom.2017.03.312
  103. Ziyao Ma, Lihua Zhan, Chunhui Liu, Lingzhi Xu, Yongqian Xu, Peipei Ma, and Jianjun Li, Stress-level-dependency and bimodal precipitation behaviors during creep ageing of Al–Cu alloy: experiments and modeling, International Journal of Plasticity, 110: 183 (2018); https://doi.org/10.1016/j.ijplas.2018.07.001
  104. Antonio Gloria, Roberto Montanari, Maria Richetta, and Alessandra Varone, Alloys for Aeronautic Applications: State of the Art and Perspectives, Metals, 9, Iss. 6: 662 (2019); https://doi.org/10.3390/met9060662
  105. Peng Zhang, Kunkun Shi, Jianjun Bian, Jinyu Zhang, Yong Peng, Gang Liu, Alexis Deschamps, and Jun Sun, Solute cluster evolution during deformation and high strain hardening capability in naturally aged Al–Zn–Mg alloy, Acta Materialia, 207: 116682 (2021); https://doi.org/10.1016/j.actamat.2021.116682
  106. A.A. Kulіnіch, V.P. Gavrilyuk, O.O. Ryabіnіna, S.M. Kotlyar, Vplyv berylіyu na mekhanіchnі vlastyvostі lyvarnykh splavіv systemy Al–Mg–Zn z domіshkamy zalіza. Zbіrnik ‘Lytvo-2008’ [Infusion of beryllium on the mechanical power of liqueur alloys of the Al–Mg–Zn system with molding houses. Collection ‘Lytvo-2008’] (Zaporіzhzhya: 2008), pp. 106–108 (in Ukrainian).
  107. V.A. Efimov and A.S. Zhel’darkhanov, Tekhnologii Sovremennoy Metallurgii [Modern metallurgy technologies] (Moskva: Novyye Tekhnologii: 2004) (in Russian).
  108. P.P. Pobezhimov, L.P. Nefedova, and E.V. Belov, Metallurgiya Korrozionno-Stoykikh Alyuminievykh Splavov i Otlivok [Metallurgy of corrosion-resistant aluminum alloys and castings] (Moskva: Metallurgiya: 1989) (in Russian).
  109. N.M. Galdin, D.F. Chernega, D.F. Ivanchuk, Yu.V. Moiseev, and V.V. Chistyakov, Tsvetnoye Lit’e: Spravochnik [Non-ferrous casting: Handbook] (Moskva: Mashinostroyenie: 1989) (in Russian).
  110. F.D. Obolencev, Fizikokhimiya i Tekhnologiya Kompozitsionnogo Lit’ya [Physicochemistry and technology of composite casting] (Odessa: 1984) (in Russian).
  111. S.S. Zatulovskiy, V.Ya. Kezik, and R.K. Ivanova, Lityye Kompozitsionnyye Materialy [Cast composite materials] (Kiev: Tekhnika: 1990) (in Russian).
  112. A.A. Baranov, O.P. Mikulyak, and A.A. Reznyakov, Tekhnologiya Vtorichnykh Tsvetnykh Metallov i Splavov [Technology of secondary non-ferrous metals and alloys] (Kiev: Vishcha Shkola: 1988) (in Russian).
  113. Jovid Rakhmonov, Kun Liu, Paul Rometsch, Nick Parson, and X.-Grant Chen, Improving the mechanical response of Al–Mg–Si 6082 structural alloys during high-temperature exposure through dispersoid strengthening, Materials, 13: 5295 (2020); https://doi.org/10.3390/ma13225295
  114. Liying Cui, Zhan Zhang, and X.-Grant Chen, Microstructure and mechanical properties of novel Al–Cu–Mg–Zn lightweight entropy alloys for elevated-temperature applications, Materials Characterization, 200: 112927 (2023); https://doi.org/10.1016/j.matchar.2023.112927
  115. Liying Cui, Zhan Zhang, and X.-Grant Chen, Development of lightweight Al-based entropy alloys for elevated temperature applications, Journal of Alloys and Compounds, 938: 168619 (2023); https://doi.org/10.1016/j.jallcom.2022.168619
  116. Dong Li, Kun Liu, Jovid Rakhmonov, and X.-Grant Chen, Enhanced thermal stability of precipitates and elevated-temperature properties via microalloying with transition metals (Zr, V and Sc) in Al–Cu 224 cast alloys, Materials Science and Engineering: A, 827: 142090 (2021); https://doi.org/10.1016/j.msea.2021.142090
  117. Ling-Mei Wu, Wen-Hsiung Wang, Yung-Fu Hsu, and Shan Trong, Effects of homogenization treatment on recrystallization behavior and dispersoid distribution in an Al–Zn–Mg–Sc–Zr alloy, Journal of Alloys and Compounds, 456: 163 (2008); https://doi.org/10.1016/j.jallcom.2007.02.054
  118. Y.J. Li, A.M.F. Muggerud, A. Olsen, and T. Furu, Precipitation of partially coherent α-Al(Mn, Fe)Si dispersoids and their strengthening effect in AA 3003 alloy, Acta Materialia, 60: Iss. 3: 1004 (2012); https://doi.org/10.1016/j.actamat.2011.11.003
  119. Xiaojing Xu, Zheng Liu, Bin Zhang, Hanhui Chen, Jinsong Zhang, Tianlun Wang, Keren Zhang, Jie Zhang, and Peng Huang, Effect of Mn content on microstructure and properties of 6000 series aluminum alloy, Appl. Phys. A, 125: 490 (2019); https://doi.org/10.1007/s00339-019-2780-9