Про стрибки об’єму, ентальпії й ентропії за температури топлення, теплопровідність і термодифузію для ГЦК-Au: залежності від температури та тиску

Н. К. Хок$^1$, Б. Д. Тін$^1$, Н. Д. Хієн$^2$, Л. Х. В’єт$^3$

$^1$Національний університет освіти Ханоя, Ханой, В’єтнам
$^2$Вища школа Мак Дінь Чі, провінція Залай, В’єтнам
$^3$Університет Чан Куок Туан, Ханой, В’єтнам

Отримано 22.07.2021; остаточна версія — 01.11.2021 Завантажити PDF logo PDF

Анотація
Досліджуються температура топлення, стрибки об’єму, ентальпії та ентропії в точці топлення, ізотермічна стисливість, коефіцієнт теплового розширення, теплоємність при постійному об’ємі, Ґрюнайзенів параметер, Дебайова температура, питомий електричний опір, теплопровідність і термодифузія для ГЦК-металів з дефектами та ідеальних шляхом поєднання методи статистичних моментів, граничної умови абсолютної стабільности кристалічного стану, рівняння Клапейрона–Клаузіуса, Дебайового моделю, Ґрюнайзенового рівняння, закону Відемана–Франца, Моттового рівняння. Проведено чисельні розрахунки для Au за високих температур і тисків. Розрахована крива топлення Au добре узгоджується з експериментами й іншими розрахунками. Одержані результати є прогнозними та спонукають до нових експериментів.

Ключові слова: стрибки об’єму, ентальпія й ентропія за температури топлення, теплопровідність, теплопровідність, метод статистичних моментів.

Citation: Nguyen Quang Hoc, Bui Duc Tinh, Nguyen Duc Hien, and Le Hong Viet, On the Jumps of Volume, Enthalpy and Entropy at the Melting Point, the Thermal Conductivity and Thermal Diffusivity for F.C.C. Au: the Temperature- and Pressure-Dependences, Progress in Physics of Metals, 22, No. 4: 511–530 (2021); doi: 10.15407/ufm.22.04.511


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